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AP Chemistry
07. Exam Review 7: Solutions
Molality
Expresses concentration in terms of mass of a solvent.
m = moles of solute/kilograms of solvent
Mole fraction
Mole Fraction = moles of substance S/total number of moles in solution
Solutes and Solvents
Like dissolves like. Free ions in a solution are called electrolytes because they can conduct electricity.
vant Hoff factor (i) tells how many ions one unit of a substance will dissociate into a solution. (ex. CaCl
2
i = 3)
Colligative properties: properties that depend on the number of
solute particles
in a solution, not the identity of particles.
Boiling Point Elevation/Freezing Point Depression
When a solute is added to a solution, the boiling point of the solution increases, and the freezing point of the solution decreases.
ΔT = ik
b/f
m
Vapor Pressure Lowering
When a solute is added to a solution, the vapor pressure of the solution will decrease (boiling point is increased).
P = XP
o
P - vapor pressure of soluton, X - mole fraction of the
solvent
, P
o
- vapor pressure of pure solvent
Solubility Product
Measure of the extent of a salts dissociation in solution. The greater the value, the more soluble the salt.
More in Review 8.
Soluble Ions
NO3
ClO3/ClO4
C2H3O2
Br, Cl, I
SO4
Insoluble Ions
OH, PO4, CO3, S, SO3. EXCEPT those containing alkali metals and ammonium
Solublility of Gases
The lower the temperature and the higher the pressure of the gas, the more soluble the gas will be.
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