Dislocation
A linear or one-dimensional defect around which some of the atoms are misaligned.  
Imperfections in Solids
Impurities in Metals
A pure metal (consisting of only one type of atom) is impossible.  
Alloys
Intentionally adding impurity atoms to impart specific characteristics to the material. 
Solid Solution 
Adding impurity results in the formation of a solid solution and/or a second phase
Solute vs Solvent
Solvent - material present in greater amount
Solute - material with minor concentration 
Types of impurity point defects
Substitutional and interstitial.
Substitutional
Impurity atoms substitute for host atoms.  The degree to which solute atoms dissolves into solvent is determined by atomic size factor (smaller difference more dissolve), crystal structure (must be same), electronegativity (small difference), valences (higher valency the higher metal will dissolve).
- Typically metals, but can also be ceramics (must have nearly same ionic size and charge as host)
Interstitial
Impurity atoms fill voids among host atoms.  
- The lower the atomic packing factors, the greater the voids (ie. NOT metals (which have high atomic packing factors)!).  
- Smaller atomic diameter of impurity, the greater the dissolution 
- Can be metals, and also ceramics 
Ceramics
In order for impurities to occur in ceramics: 
1) ionic size and charge of impurity must be similar to host ions
2) for an impurity ion having a diff charge, crystal must compensate for this difference in charge (neutrality must be maintained)
Main Idea
Polymers 
Both types of defects can be found in the crystalline regions of polymeric materials, similar to metals.  
Impurities in Polymers
Point defects in polymers can be similar to metals in crystalline regions of polymeric materials.  
- Chain ends considered defects (bc they're so chemically dissimilar to chain units). Vacancies are associated with chain ends.
- Additional defects can result from branches in polymer chain/chain segments that stick out. 

Linear Defects
Edge dislocation
A linear defect that centers on the line is defined along the end of the extra half-plane of atoms (dislocation line)
Screw Dislocation
Formed by shear stress (like trying to unscrew the crystal, results in shear stress)
Planar Defects
Interfacial Defects
Boundaries that have two dimensions and normally separate regions of the materials that have different crystal structures and/or crystallographic orientations. 
Grain boundaries
Boundary separating two small grains or crystals having different crystallographic orientations in polycrystalline materials. 
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